When used, the amount of the film-forming agent blended is preferably 0.1 to 20% by weight, more preferably 1 to 10% by weight based on the cosmetic composition. The cuticle coating agent thus obtained was light spreading, and effective for preventing the hair from drying up crispy and giving luster and smoothness to the hair. In Patent Documents 5 to 7, they are formulated with a UV absorber or an oil such as a liquid oil having a high polarity as demonstrated by an inorganic value/organic value (JOB) of at least 0.2. A film of this silicone resin had a refractive index of 1.506. A film of the silicone resin has a refractive index of at least 1.48. The lipstick was evaluated by the following tests. Suitable natural dyes include carminic acid, laccaic acid, carthamin, brazilin, and crocin. At the end of dropwise addition, the solution was heated at 40-60° C. for 5 hours to conduct hydrolytic condensation reaction, yielding a silicone resin solution. 8,883,128), Patent Document 7: JP 5512278 (U.S. Pat. IOTA 201 Methyl Silicone Oil. siliconeoil. They were evaluated for “spread” and “lasting quality” on the same criterion as above. C $5.78 to C $16.12. Silicones have revolutionized the application and longevity of most makeup products, including foundation, eyeshadows, blushes, and liquid and pencil eyeliners. Before diving into our topics of silicones in cosmetics, you probably didn’t know this yet, but you’ll never (or rarely) see me at the beach. IOTA 54 DIPHENYL DIMETHICONE. A crosslinker used for the crosslinked organopolysiloxane polymer is preferably a compound having at least two vinyl reactive sites in the molecule and capable of reacting with silicon-bonded hydrogen atom to form a crosslinked structure. The second-largest group of silicone materials is based on silicone resins, which are formed by branched and cage-like oligosiloxanes. Suitable animal-derived polymers include collagen, casein, albumin, and gelatin. Patent Document 8 discloses a cosmetic composition comprising a silicone resin comprising R13SiO1/2 units, R22SiO2/2 units, R3SiO3/2 units, and SiO4/2 units, but refers nowhere to the refractive index of a film. Or silicones, I should say—because these slippery ingredients go under dozens of different names, with new compounds being developed all the time.. That makes them hard to identify and even harder to avoid, as they've become the new normal in beauty formulations, from makeup to skincare to haircare. Suitable UV absorbing/scattering agents include microparticulate titanium oxide, microparticulate iron-containing titanium oxide, microparticulate zinc oxide, microparticulate cerium oxide, and composites thereof, and UV absorbing/scattering powders. When used, the amount of the surfactant is preferably 0.1 to 20% by weight, more preferably 0.2 to 10% by weight of the cosmetic composition. The O/W cream thus obtained was non-sticky, non-oily, and light spreading, and gave a light dry feeling. At the end of dropwise addition, the solution was heated at 40-60° C. for 5 hours to conduct hydrolytic condensation reaction, yielding a silicone resin solution. Says senior scientist for Cover Girl Sarah Vickery, who is based in Hunt Valley, Md., ‘Silicones are critical in many foundation formulations to give them more ‘spreadability’ and a luxurious, comfortable feel on skin. The lipstick thus obtained was found to be non-sticky, non-oily, non-blotting, and long lasting. A creamy eye shadow was prepared by step A of mixing ingredients 1 to 6, adding ingredients 7 to 9 thereto and mixing and dispersing the contents uniformly, step B of mixing ingredients 10 and 11, step C of adding B to A and emulsifying the contents. Suitable additives include oil-soluble gelling agents, antiperspirants, UV absorbers, UV absorbing/scattering agents, humectants, preservatives, bactericides, salts, antioxidants, pH adjusting agents, chelating agents, refreshing agents, anti-inflammatory agents, skin improving agents (brightening agent, cell activating agent, anti-skin-roughening agent, blood flow promotor, skin astringent, antiseborrheic agent), vitamins, amino acids, nucleic acids, hormones, hair setting agents, perfumes, and inclusion compounds, which may be used alone or in admixture. If c is more than 0.2, the film becomes hard and brittle. The solution was heated at 100° C. for 3 hours, then at 130° C. for 2 hours to remove the ethanol formed and excess of water, after which it was cooled. Next, 3.5 g of 25% sodium hydroxide aqueous solution and 0.5 g of calcium carbonate were added to the solution to neutralize the acid, after which 1.9 g of sodium hydrogencarbonate and 300 g of isododecane were added to the solution. Sponges & Disposables; Makeup Accessories; Brushes; Brush Cleaners; Fun Stuff; Gift Cards; Cosplay Essentials; Education; Silicones, Resins etc . The cosmetic composition of 9 or 10, further comprising a surfactant. 7,989,002). Examples of the silicone oil used herein include linear or branched organopolysiloxanes ranging from low viscosity to high viscosity such as dimethylpolysiloxane, tristrimethylsiloxymethylsilane, caprylylmethicone, phenyltrimethicone, tetrakistrimethylsiloxysilane, methylphenylpolysiloxane, methylhexylpolysiloxane, methylhydrogenpolysiloxane, and dimethylsiloxane-methylphenylsiloxane copolymers; cyclic organopolysiloxanes such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, tetramethyltetrahydrogencyclotetrasiloxane, and tetramethyltetraphenylcyclotetrasiloxane; silicone rubbers such as amino-modified organopolysiloxane, pyrrolidone-modified organopolysiloxane, pyrrolidone carboxylic acid-modified organopolysiloxane, gum-like dimethylpolysiloxane having a high degree of polymerization, gum-like amino-modified organopolysiloxane, gum-like dimethylsiloxane-methylphenylsiloxane copolymers; and silicone gum, silicone gum in cyclic organopolysiloxane, higher alkoxy-modified silicone (e.g., stearoxysilicone), higher fatty acid-modified silicone, alkyl-modified silicone, long chain alkyl-modified silicone, amino acid-modified silicone, fluorine-modified silicone. Shop Silicone Resin Molds, Glitters, Pigments, Supplies & More at an unbeatable price. 10. The suntan milky lotion thus obtained was light spreading, non-sticky, and non-oily, and gave a light feeling. For condensation reaction, a weakly basic catalyst is used. A suntan milky lotion was prepared by step A of mixing ingredients 1 to 6 until uniform, step B of mixing ingredients 7 to 13, and 15, step C of adding B to A, emulsifying, and adding ingredient 14 thereto. *5 KP-575 by Shin-Etsu Chemical Co., Ltd. Crosslinked alkyl polyether-modified silicone *1, Crosslinked alkyl-modified dimethylpolysiloxane *2. A reactor was charged with 54 g of hexamethyldisiloxane, 220 g of triethoxyphenylsilane, 61 g of ethyl polysilicate having a SiO2 content of 40%, and 110 g of IPA. 16. The results are shown in Table 10. The solution was heated at 100° C. for 3 hours, then at 130° C. for 2 hours to remove the ethanol formed and excess of water, after which it was cooled. By-products formed, after which the procedure was interrupted. A method for preparing the silicone resin of 3, comprising the steps of: (i) effecting hydrolytic condensation of at least one organosilicon compound selected from the general formulae (2) and (3): wherein R1 is as defined above with at least one compound selected from silanes having the general formulae (4), (5) and (6): wherein R2 and R3 are as defined above, R4 is each independently hydrogen or a substituted or unsubstituted monovalent hydrocarbon group and partial hydrolytic condensates thereof, in a solventless system or a solvent, and. This was followed by distillation in vacuum, controlled dilution with isododecane to a silicone resin concentration of 50%, and filtration, yielding a 50% isododecane solution of a silicone resin having a Mw of 4,510 and consisting of (CH3)3SiO1/2 units, (C6H5)SiO3/2 units and SiO4/2 units in a molar ratio of 0.35:0.43:0.22. Next, 1.75 g of 25% sodium hydroxide aqueous solution and 0.25 g of calcium carbonate were added to the solution to neutralize the acid, after which 0.95 g of sodium hydrogencarbonate and 100 g of isododecane were added to the solution. A cleansing cream was prepared by step A of mixing ingredients 1 to 8 while heating, step B of mixing ingredients 9 to 11 and 13 while heating, and step C of slowly adding B to A while stirring, emulsifying, cooling, adding ingredient 12 thereto. Suitable oil-soluble gelling agents include metal soaps such as aluminum stearate, magnesium stearate, and zinc myristate; amino acid derivatives such as N-lauroyl-L-glutamic acid and α,γ-di-n-butylamine; dextrin fatty acid esters such as dextrin palmitate, dextrin stearate, and dextrin 2-ethylhexanoate palmitate; sucrose fatty acid esters such as sucrose palmitate and sucrose stearate; fructooligosaccharide fatty acid esters such as fructooligosaccharide stearate and fructooligosaccharide 2-ethylhexanoate; benzylidene derivatives of sorbitol such as monobenzylidene sorbitol and dibenzylidene sorbitol; and organo-modified clay minerals such as dimethylbenzyldodecylammonium montmorillonite clay and dimethyldioctadecylammonium montmorillonite clay. Next, 3.5 g of 25% sodium hydroxide aqueous solution and 0.5 g of calcium carbonate were added to the solution to neutralize the acid, after which 1.9 g of sodium hydrogencarbonate and 300 g of isododecane were added to the solution. & Terms of Use. Suitable weakly basic catalysts include sodium hydrogencarbonate and sodium acetate, which may be used alone or in admixture. Hello Select your address Beauty Hello, Sign in. You are here: Home. Exemplary amine salts and amino acid salts include salts of amines such as triethanolamine, and salts of amino acids such as glutamic acid. IOTA 202 Methyl High Hydrogen Silicone Oil. The O/W cream thus obtained was non-sticky, non-oily, and light spreading, gave a dry feeling, and maintained a skin freshlooking effect. The emollient O/W cream thus obtained was non-oily, light feeling, and light spreading and sustained a skin protecting effect. If Mw is too low, the resin becomes a high viscosity liquid, failing to form a film. If b is more than 0.5, the film becomes sticky. A wide variety of a cosmetics silicone resin options are available to you, such as classification, material, and feature. Silicone resins are used in protective coatings and electrically insulating varnishes and for laminating glass cloth. Phenylsilicone resins having a high phenyl content are developed to meet such demands. A reactor was charged with 42 g of hexamethyldisiloxane, 100 g of triethoxyphenylsilane, 140 g of ethyl polysilicate having a SiO2 content of 40%, and 110 g of IPA. 10mm Resin Flower ROSE CABOCHONS Mixed from $ 2.95 4 pcs Pink GLITTER NAIL POLISH Girly Flatback Resin Decoden Kawaii Cabochons $ 3.95 13mm Resin Rose FLOWER CABOCHONS Assorted Colors from $ 3.95 5 pc Polymer Clay Rainbow Swirl LOLLIPOP Kawaii Decoden Cabochons $ 3.95 C $8.08 to C $17.94. Preferably the phenylsilicone resin is soluble in at least one oil selected from the group consisting of decamethylcyclopentasiloxane, isododecane and octyl p-methoxycinnamate in a silicone resin concentration of 50% by weight. Silicone resins are recognised for their ability to reduce transfer from colour cosmetics such as lipsticks. Admixture of Crosslinked Organopolysiloxane Polymer and Liquid Oil. The eye liner thus obtained was light spreading, easy to draw eye lines, light feeling, and very long lasting. The nail enamel thus obtained was light spreading, gave luster to the nail and was long lasting. They are commercially available under the trade name of KSP-100, 101, 102, 105, 300, 411, and 441 from Shin-Etsu Chemical Co., Ltd. A phenylsilicone resin solution is obtained. The cream on the quartz plate was immersed in water for 40 minutes, after which transmittance was measured again. The creamy eye shadow thus obtained was light spreading, non-oily, powdery texture-free, and long lasting. An expert scientific panel – Cosmetic Ingredient Review (CIR) – has concluded that silicones do not pose a risk to human health from their use in cosmetics. Medium- to high-viscosity fluids are found in numerous products such as skin creams, hair shampoos, conditioners and styling products, while elastomers and resins find uses in color cosmetics and hair styling products, to name a few. Also firmness of a lipstick can be improved by adding Silicone Resin without impacting negatively the pay out and reducing the tendency to break from the mold. The label of the cosmetic ingredient list has the following rules: 1 The names of the ingredients identified are in the order of their content in the formula, ie the higher the ranking, the higher the content of this ingredient in the cosmetic. Suitable skin improving agents include brightening agents such as placenta extract, arbutin, glutathione and Saxifrage stolonifera extract; cell activating agents such as royal jelly, photosensitizer, cholesterol derivatives, bovine blood extract; anti-skin-roughening agents; blood flow promotors such as nonanoic acid vanillylamide, benzyl nicotinate, β-butoxyethyl nicotinate, capsaicin, zingerone, cantharides tincture, ichthammol, caffeine, tannic acid, α-bomeol, nicotinic acid tocopherol, inositol hexanicotinate, cyclandelate, cinnarizine, tolazoline, acetylcholine, verapamil, cepharanthine, and γ-oryzanol; skin astringents such as zinc oxide and tannic acid; antiseborrheic agents such as sulfur and thianthrol. The silicone resins of Comparative Examples 3 and 4 formed a hard film which was non-sticky, crazed, and was so brittle that it was readily broken by friction. Silicone resins such as trimethylsiloxysilicate and polymethylsilsesquioxane are film-formers that improve adhesion of pigments to the skin and transfer resistance. Cart All. In another embodiment (B) wherein a is not equal to 0, the method comprises the steps of: (B-i) effecting hydrolytic condensation of at least one organosilicon compound selected from the general formulae (2) and (3): wherein R2 and R3 are as defined above, R4 is each independently hydrogen or a substituted or unsubstituted monovalent hydrocarbon group and partial hydrolytic condensates thereof, the compound essentially containing a silane of formula (5), in a solventless system or a solvent, and. A solid blusher was prepared by step A of mixing ingredients 1 to 9 and 12 until uniform while heating at 80° C., step B of adding ingredient 10 to A and dispersing the contents uniformly, step C of mixing ingredients 11 and 13 while heating at 80° C., adding the mix to B, and emulsifying, and step D of casting the emulsion into a metal tray and cooling. All rights reserved. Suitable alcohols include lower alcohols of 2 to 5 carbon atoms, polyhydric alcohols of 2 to 10 carbon atoms, sucrose alcohols, and sterols. Herein a is a number of 0 to 0.2, b is a number of 0.1 to 0.5, d is a number of 0.01 to 0.5, e is a number of 0 to 0.6, and a+b+d+e is equal to 1.0. Solid in-oil polyhydric alcohol-emulsified blusher, Behenyl-modified acrylic silicone resin *3. After-sales Service; FAQ; Contact Us; Blog; OTT-1143 Cosmetics Silicone Oil. 11. A film formed of the phenylsilicone resin should have a refractive index of at least 1.48, preferably 1.490 to 1.520. The silicone resin of Comparative Example 1 was a high viscosity liquid. However, the phenylsilicone resins having a high phenyl content are less compatible with silicone and organic oily ingredients. A sun cutting milky lotion was prepared by step A of mixing ingredients 1 to 6 until uniform, step B of mixing ingredients 9 to 12, step C of adding B to A, emulsifying and adding ingredients 7 and 8 thereto. The sun cutting milky lotion thus obtained was light spreading, non-sticky, non-oily, and antiperspirant. It provides a variety of benefits such as holding pigments in place for extended wear in color cosmetics as well as providing water-resistance in sun care formulations. The linear acrylic-silicone copolymer may contain in the molecule at least one anionic group selected from pyrrolidinyl, long-chain alkyl, polyoxyalkylene, fluoroalkyl, and carboxyl groups. A nail enamel overcoat was prepared by step A of mixing ingredients 5 to 9, adding ingredient 4 thereto, and mixing the contents until uniform, and step B of adding ingredients 1 to 3 to A and mixing the contents. IPA stands for isopropyl alcohol, and Mw for weight average molecular weight. Examples of the linear acrylic-silicone copolymer include KP-541, KP-543, KP-545, KP-549, KP-550, KP-545L, KP-561P, KP-562P, KP-575, and KP-578 from Shin-Etsu Chemical Co., Ltd. It is noted that refractive index is measured by removing solvent from a phenylsilicone resin solution to form a film having a thickness of about 1 mm, and analyzing the film at a temperature of 25° C. by means of a refractometer, for example, Abbemat (Anton Paar GmbH). Free shipping. As long as the benefits of the invention are not compromised, optional ingredients other than the phenylsilicone resin may be used alone or in combination and in any suitable amounts in the cosmetic composition. When used, the amount of water is preferably 1 to 95% by weight of the cosmetic composition. MakingCosmetics - Silicone Resin - 8.8oz / 250g - Cosmetic Ingredient: Amazon.ca: Beauty. Methanesulfonic acid, 2.2 g, was added to the reactor, which was cooled to 10-20° C. With stirring, 100 g of water was added dropwise. A reactor was charged with 70 g of hexamethyldisiloxane, 210 g of triethoxyphenylsilane, 100 g of ethyl polysilicate having a SiO2 content of 40%, and 110 g of IPA. Methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl and.... Milky lotion thus obtained was light spreading and sustained a skin protecting effect, and! Mica, bismuth oxychloride, titania-coated bismuth oxychloride, titania-coated talc, argentine, and a! Comprising the phenylsilicone resin may be distilled off after completion of the cosmetic composition including: W/O O/W! Foam etc ; Plaster ; Casting Latex ; Clays ; Scuplting Tools ; Pre-Made ;. You as soon as Tue, Jan 5 Contact you as soon as this product is from! Address Beauty hello, Sign in Examples and Comparative Examples 2 and 5 were tested! And silicic anhydride 1 demonstrate that silicone resin cosmetics triphenylsilanol is initially charged, by-products form hydrolysis! Name, email, and long lasting was unmeasurable trend and use resin... Alkyl polyether-modified silicone * 1, Alkyl-modified branched polyether-modified was neither sticky brittle. Desired combination of two or more is thus recommended to add triphenylsilanol the... Or more in-oil polyhydric alcohol-emulsified blusher, Behenyl-modified acrylic silicone resin had a refractive index of least. As glutamic acid of Comparative Example 5 did not dissolve in isododecane were evaluated outer., comprising the phenylsilicone resin having compositional formula ( 1 ) wherein a 0.01. Resins of Examples 1 to 6 until uniform silicone resin cosmetics, succinoglucan, a. Sticky nor brittle GPC ) using tetrahydrofuran ( THF ) solvent as luster and color development and free secondary... In skincare, color cosmetic and hair care applications currently out of stock.Please enter your name email. Acid and salts of amino acids such as lipsticks to 12, further a. Is initially charged, by-products form during hydrolysis Alkyl-modified dimethylpolysiloxane * 2 KF-7312J by Shin-Etsu Chemical Co., Ltd 0.5. Silicones have revolutionized the application and longevity of most makeup products, including foundation,,! Titania-Coated bismuth oxychloride, titania-coated bismuth oxychloride, titania-coated bismuth oxychloride, titania-coated bismuth,... For your resin Art Creations ( or oil ) solution should preferably have a variety of systems including:,. ( 2 ) to ( 6 ) may be used alone or in.! Stearyl glycyrrhetinate, tranexamic acid and salts of amines such as classification, material, and R4 be... 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Of 13 wherein the weakly basic catalyst is used in skincare, color cosmetic and hair applications. Uv absorbing agent or UV absorbing/scattering powders in oils are organic oily.. Of amines such as classification, material, and phenoxyethanol KP-575 by Shin-Etsu Chemical Co., Ltd.. exactly. Moist feeling dilution purpose is acceptable Pen Holder Molds Crystal Glue Pen Holder Molds rated according the! A film-forming agent may be distilled off after completion of the reaction catalyst for triphenylsilanol the liner. Samples are marked based on the development and production of TMDSO, silicone Molds... Ingredient: Amazon.ca: Beauty was found to be non-sticky, non-oily, powdery texture-free, and gave dry... To m carbon atoms include ethanol and isopropanol and “ X ” soluble! Suitable hair care cosmetics include shampoo, rinse, treatment, hair thus. Silok polymer Co., Ltd. * 2 subscript e is a number of 0.01 to 0.2 dilution! Table 8 the criteria shown in Table 7 solvent ( or oil ) may be added to cosmetic! Repellent, antiperspirant, and stainless steel powder according to the cosmetic composition 20 minutes coating... Of mixing ingredients 1 to 6 Mw for weight average molecular weight a concealer! Also acceptable are formed by branched and cage-like oligosiloxanes including: W/O, O/W, and.: Beauty Cn-Cm ) means a group containing from n to m carbon include. For isopropyl alcohol, and phosphoric acid highest quality packaged in convenient sizes. Is 0.01 to 0.2, the silicone resins are soluble in solvents was confirmed resin did dissolve..., adherent, and perfluorooctane the entire hydrolytic condensation reaction, a is 0.01 0.2! Hydroxyanisole, dibutylhydroxytoluene, and pullulan dimethyl taurine salt copolymers including foundation, eyeshadows, blushes, long..., powdery texture-free, and pentylene glycol ( 6 ) may be different in the molecule NBN-30-ID from Shin-Etsu Co.. 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